These can be horribly difficult to remove, as you have found.
You need some judicious use of hammer and drift to help you out too.
Grade 8's or even 9's are the first place to start, then you will need to grease/oil the landing point of the screw to reduce friction and lastly, load them up and whack them with either a spreader drift (like the chisel you used) or vertically catching the gap between the 2 parts. On the center pulley, you need to get down past the hub and get the whack delivered to the pulley - think pipe ground to fit between the two parts. Take your time and don't get too aggressive with the hammer. Unload them(loosen bolts) then reload and repeat the whacks. Those vibrations tend to help shake the sheave loose. It can take 100 whacks or more to get them to moving. I wailed on a PTO pulley, which is the same patent, with a 2 lb hand sledge and drift right at the center of the hub. I hit it so hard I was sure it would break, but my IH tech assured me that was what it would take and after about 15 minutes it almost fell off.
When you put it back together, don't just pull the bolts down and go. It takes about 10 rounds of torque and retorque back and forth on the bolts to get everything to seat and get tight. I did about 4 rounds, thought it had stopped moving, and in about 30 seconds of mowing, the pulley started walking off the shaft.
I've never tried heat on those before, but you may try the blue wrench on it.....the pulley is cast, so you shouldn't have an issue drawing any HT out of the part.